Industry

Refractories for Chemical & Petrochemical Applications

Refractories in chemical and petrochemical plants line coal water slurry and residue oil gasifiers, secondary reformers, carbon black reactors, hydrogen production furnaces, gas generators and cracking furnaces. The technical reference's gasifier schemes build the lining from a high chrome brick working face, a chrome corundum brick backing, an alumina bubble brick insulating layer, refractory castables and a ceramic fibre coating or felt against the shell.

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Refractory Requirements — Chemical & Petrochemical

The petrochemical technical reference is organised around equipment, and its most useful pages are four lining schemes: the Texaco coal water slurry gasifier, the four-jets coal water slurry gasifier, the secondary reformer and the Texaco residue gasifier. Each scheme is a legend of named layers rather than a product list, and the four are deliberately different from one another.

The two coal water slurry schemes build outwards from a high chrome brick working face through chrome corundum brick, alumina bubble brick and refractory castables to a ceramic fiber coating, with the four-jets version adding a ceramic fiber felt. The residue gasifier scheme replaces the chrome working face with high purity corundum brick and inserts a light-weight insulating brick layer. The secondary reformer scheme is simpler again: refractory castables, corundum brick and refractory insulating castables.

The table below follows those legends and the application sentence printed on each product page. Service-life figures and plant counts that appear in the technical reference are excluded from this website and are not quoted. Where a layer is named only in general terms, the term is shown as it stands rather than resolved to a specific product.

Where Refractories Are Used

4 equipment and zones

  1. Coal Water Slurry Gasifier

    Texaco Coal Water Slurry Gasifier / 4 Jets Coal Water Slurry Gasifier

    The technical reference gives two schemes. Both build the lining in layers from the process side outwards: high chrome brick, chrome corundum brick, alumina bubble brick, refractory castables and a ceramic fibre coating; the four-jets scheme adds a ceramic fibre felt.

  2. Residue Oil Gasifier

    Texaco Residue Gasifier

    A different lining from the coal water slurry scheme: corundum brick at the working face, then alumina bubble brick, light-weight insulating brick, refractory castables and refractory fibre.

  3. Secondary Reformer

    Refractories Conformation Scheme for Secondary Reformer

    The technical reference's simplest scheme, built from refractory castables, corundum brick and refractory insulating castables.

  4. Reactors, Hydrogen Furnaces and Cracking Furnaces

    The technical reference names the carbon black reactor, the hydrogen production furnace, the gas generator, the cracking furnace and the intermediate frequency reactor on its product pages.

Refractory Selection by Equipment

Coal Water Slurry Gasifier

6
ZoneRefractory typeRISING product
Working lining, process sideHigh Chrome Brick
Backing liningChrome Corundum Brick
Insulating layerAlumina Bubble Brick
Between the brick lining and the shellRefractory CastablesOn request
Against the shellCeramic Fiber CoatingOn request
Against the shell (four-jets scheme)Ceramic Fiber Felt

Residue Oil Gasifier

5
ZoneRefractory typeRISING product
Working lining, process sideCorundum Brick (high purity, Al₂O₃ ≥ 99 %)
Insulating layerAlumina Bubble Brick
Insulating layerLight-weight Insulating Brick
Between the brick lining and the shellRefractory CastablesOn request
Against the shellRefractory Fiber

Secondary Reformer

3
ZoneRefractory typeRISING product
Working liningCorundum Brick
LiningRefractory CastablesOn request
Insulating layerRefractory Insulating Castables

Reactors, Hydrogen Furnaces and Cracking Furnaces

12
ZoneRefractory typeRISING product
Gasifier and oil gas pressurized gasifier backing or working lining; chemical reaction furnaceChrome Corundum Brick (Cr₂O₃ 5–30 %)
Hydrogen production furnace, gasifier and carbon black reactor working and backing lining; intermediate frequency reactor insulation liningAlumina Bubble Brick
Carbon black reactor and petrochemical gasifierAlumina Bubble Castable
Gasification furnaces and gas generators; thermal insulation lining of coal black furnacesMullite Light-weight Insulating Bricks
Gasification furnaces and gas generators; thermal insulation lining of coal black furnacesAlumina Light-weight Insulating Bricks
Gasifier and cracking furnace insulation layer; expansion jointsCeramic Fiber Blanket and Board
Working layer of cracking furnacesCeramic Fiber Module
High-temperature working liningCorundum Mullite Bricks
Monolithic working liningCorundum Mullite Series CastableOn request
Carbon black reactorChrome Corundum CastablesOn request
InsulationMullite Insulating Refractory CastablesOn request
InsulationLight-weight Insulating Castables

Refractory types are listed as named in RISING's technical references. A row reads "On request" where the material has no catalogue page yet.

Lining System Overview

Coal water slurry gasifier liningThe lining layers named in the reference legend, from the process side outwards. Layer thicknesses are indicative only, not dimensions.01High Chrome BrickWorking lining, process side02Chrome Corundum BrickBacking03Alumina Bubble BrickInsulating layer04Refractory Castables05Ceramic Fiber Coating / Ceramic Fiber FeltAgainst the shell
Coal water slurry gasifier liningThe lining layers named in the reference legend, from the process side outwards. Layer thicknesses are indicative only, not dimensions.Reference documents: RISING chemical and petrochemical refractory technical reference

Recommended Refractory Materials

12 linked products

View all products for this industry

Technical Considerations

Lining varies by gasifier type
The technical reference gives four separate conformation schemes. The coal water slurry gasifier and the residue oil gasifier do not share a working lining: the first is lined with high chrome brick, the second with high purity corundum brick. No single lining is presented as suitable for all chemical furnaces.
Where high chrome brick is used
The technical reference states that high chrome brick is used as the working lining of coal water slurry gasifiers, petroleum coke pressurized gasifiers and other melting devices where acid alkali slag corrosion is serious.
Where high purity corundum brick is used
The technical reference states that high purity corundum brick is used in gasifiers and gas generators in the petrochemical industry, carbon black reactors in the chemical industry and high-temperature furnace linings in the ceramic industry.

Also supplied on request

Further refractory types used in this industry that do not have a catalogue page yet. Each is supplied and quoted on request.

  • Refractory Castables as an unqualified lining layer in the gasifier and reformer schemes
  • Ceramic Fiber Coating (陶瓷纤维涂料) against the gasifier shell
  • Corundum Mullite Series Castable (RSCMC-72 / RSCMC-88)
  • Chrome Corundum Castables (RS3C-5 / RS3C-12 / RS3C-20)
  • Mullite Insulating Refractory Castables (RSIRC series)
  • Ceramic Fiber Felt as a form distinct from blanket and board

Reference documents

  • RISING chemical and petrochemical refractory technical reference

Technical Consultation

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